Of the six electron groups, five are bonding and one is a nonbonding lone pair of electrons which produces square pyramidal molecular geometry. Next, compare the electron groups surrounding the central atom to identify the molecular geometry of BrF5. The bromine atom has one non-bonding lone pair of electrons. Each fluorine atom has three non-bonding lone pairs of electrons. PICTURED: Five fluorine atoms are single bonded to one central bromine atom. Thus, a BrF5 molecule has a total of 42 valence electrons, 7+7(5)=42, as shown in the Lewis structure of BrF5. Fluorine and bromine atoms each have seven valence electrons. Begin by counting the number of valence electrons in BrF5.
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